Green synthesis of MIL-100(Fe) metal-organic frameworks as a carrier for chloroquine delivery
470 viewsDOI:
https://doi.org/10.54939/1859-1043.j.mst.76.2021.61-67Keywords:
MIL-100(Fe); Green process; Ultrasonic; Chloroquine.Abstract
The metal-organic framework MIL-100(Fe) was synthesized by the green process using the ultrasonic method and water. By using this approach, the energy consumption was reduced by 100 times compared to the hydrothermal method. The prepared MIL-100(Fe) was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET surface area measurements. The XRD pattern showed characteristic peaks of MIL-100 (Fe) with the main peaks at 6.3o, 10.3o, 11.1o, and 20.1o. The prepared MIL-100(Fe) was of particle size in a range of from 100 nm to 200 nm, and surface area of 950 m2/g with a pore volume of 0.52 cm3/g. The obtained MIL-100 (Fe) showed a high loading capacity for the chloroquine drug with a maximal capacity of 555 mg/g.
References
[1]. Paul T. Anastas and John C. Warner, Green Chemistry: Theory and Practice. Oxford University Press: Oxford, 2000.
[2]. Helge Reinsch, “Green” Synthesis of Metal-Organic Frameworks. European Journal of Inorganic Chemistry, 2016. 2016(27): p. 4290-4299.
[3]. Radwa M Ashour, Ahmed F Abdel-Magied, Qiong Wu, Richard T Olsson, and Kerstin Forsberg, Green Synthesis of Metal-Organic Framework Bacterial Cellulose Nanocomposites for Separation Applications. J Polymers, 2020. 12(5): p. 1104.
[4]. K. Shen J. Chen, Y. L, Greening the processes of metal-organic framework synthesis and their use in sustainable catalysis. ChemSusChem, 2017. 10: p. 3165–3187.
[5]. Yuxin Liang, Haibo Huang, Luqing Kou, Feng Li, Jian Lu, Hai− Lei Cao, and Design, Synthesis of Metal–Organic Framework Materials by Reflux: A Faster and Greener Pathway to Achieve Super-Hydrophobicity and Photocatalytic Application. Crystal Growth, 2018. 18(11): p. 6609-6616.
[6]. Meta A Simon, Erlina Anggraeni, Felycia Edi Soetaredjo, Shella Permasari Santoso, Wenny Irawaty, Truong Chi Thanh, Sandy Budi Hartono, Maria Yuliana, and Suryadi Ismadji, Hydrothermal synthesize of HF-free MIL-100 (Fe) for isoniazid-drug delivery. Scientific reports, 2019. 9(1): p. 1-11.
[7]. Gongsen Chen, Xin Leng, Juyuan Luo, Longtai You, Changhai Qu, Xiaoxv Dong, Hongliang Huang, Xingbin Yin, and Jian Ni, In Vitro Toxicity Study of a Porous Iron (III) Metal‒Organic Framework. Molecules, 2019. 24(7): p. 1211.
[8]. Kiros Guesh, Clarice AD Caiuby, Álvaro Mayoral, Manuel Díaz-García, Isabel Díaz, Manuel Sanchez-Sanchez, and Design, Sustainable preparation of MIL-100 (Fe) and its photocatalytic behavior in the degradation of methyl orange in water. Crystal Growth, 2017. 17(4): p. 1806-1813.
[9]. Ravi Nivetha, Kannan Gothandapani, Vimala Raghavan, George Jacob, Raja Sellappan, Preetam Bhardwaj, Sudhagar Pitchaimuthu, Arunachala Nadar Mada Kannan, Soon Kwan Jeong, and Andrews Nirmala Grace, Highly Porous MIL-100 (Fe) for the Hydrogen Evolution Reaction (HER) in Acidic and Basic Media. ACS omega, 2020. 5(30): p. 18941-18949.
[10]. Guihao Zhong, Dingxin Liu, Jianyong Zhang, and Design, Applications of Porous Metal–Organic Framework MIL-100 (M)(M= Cr, Fe, Sc, Al, V). Crystal Growth, 2018. 18(12): p. 7730-7744.
[11]. Leann Tilley, Timothy ME Davis, and Patrick G Bray, Prospects for the treatment of drug-resistant malaria parasites. Future microbiology, 2006.
[12]. Bùi Quang Phúc Hoàng Thị Kim Tuyến, Cẩm nang hướng dẫn điều trị sốt rét. Nhà xuất bản thanh niên, 2016 (in Vietnamese).
[13]. Yong Guo, Bing Yan, Yu Cheng, and Long Mu, A new Dy (III)-based metal-organic framework with polar pores for pH-controlled anticancer drug delivery and inhibiting human osteosarcoma cells. Journal of Coordination Chemistry, 2019. 72(2): p. 262-271.
