Research on selection of porous ceramic for loading metal -organic- frameworks applied in gas treatment
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https://doi.org/10.54939/1859-1043.j.mst.FEE.2022.221-229Keywords:
Porous ceramic material; Alumina ceramic; Gas treatment; CuBTC; FeBTC.Abstract
In this paper, some properties of porous insulating foam materials, available alumina particles and alumina ceramic materials were investigate. The survey results show that the insulating foam materials and alumina particles have density from 0.9 g/cm3 to 1.26 g/cm3, porosity from 50-53 %, water absorption from 39-45 % while aluminum oxide ceramic materials are made by sintering method with density from 0.64-0.73g/cm3, porosity from 69-74% and water absorption up to 108%. The results of carrying the metal-organic- framework by impregnating showed that the alumina and heat-resistant ceramic particles carried a maximum of 6% CuBTC and 8% FeBTC by mass, while the alumina ceramic material can bring up to 9% CuBTC and more than 10% FeBTC. The test results of the ability to handle NOx gas and acetone vapor show that the aluminum oxide ceramic material can adsorb up to 19 % NOx gas and 23 % acetone vapor by mass.
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