Synthesis of nanocomposites material Fe/ GNPs/ Porphyrene and the electrochemical properties investigation

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Authors

  • Nguyen Thi Xuan Quynh School of Chemical Engineering, Hanoi University of Science and Technology
  • Le Long Vu School of Chemical Engineering, Hanoi University of Science and Technology
  • Nguyen Thuy Trang School of Chemical Engineering, Hanoi University of Science and Technology
  • Khong Manh Hung Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Nguyen Lan Huong School of Biotechnology and Food Technology, Hanoi University of Science and Technology
  • La Duc Duong Institute of Chemistry and Materials, Academy of Military Science and Technology
  • Dang Trung Dung (Corresponding Author) School of Chemical Engineering, Hanoi University of Science and Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.89.2023.60-66

Keywords:

: zero valent iron; graphene; porphyrin; electrochemical properties; electrochemical sensors

Abstract

Electrochemical sensors are currently being developed and widely applied in many fields with new materials to increase the accuracy and selectivity of the method. In this study, Fe/GNPs materials were synthesized from green chemistry method, combined with recombinant TCPP process to create Fe/GNPs/TCPP nanocomposite materials. The structure and morphology of the formed products were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy. The morphological and structural analysis results of the products showed that Fe/GNPs/TCPP nanocomposites were formed from nano-structured zero valent iron particles with an average size of 15-60 nm uniformly distributed on the surface of graphene plates 2-10 nm thick, interspersed with porphyrin nanofibers with a diameter of 30 nm. The materials were investigated and evaluated for their electrochemical properties through cyclic potential scanning (CV), electrochemical impedance spectroscopy (EIS) on a three-electrode electrochemical system. The  electrochemical analysis results have demonstrated that Fe/GNPs/TCPP nanocomposite materials have good properties suit for application as electrochemical sensors in the analysis of residues of antibiotics, pesticides in agricultural production.

References

[1]. Pham, T.N., et al., "Advances in magnetic field-assisted electrolyte's physicochemical properties and electrokinetic parameters: A case study on the response ability of chloramphenicol on Fe3O4@carbon spheres-based electrochemical nanosensor". Analytica Chimica Acta. 1229: p. 340398, (2022). DOI: https://doi.org/10.1016/j.aca.2022.340398

[2]. Chen, A. and P. Holt-Hindle, "Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications". Chemical Reviews. 110(6): p. 3767-3804, (2010). DOI: https://doi.org/10.1021/cr9003902

[3]. Yogeswaran, U., S. Thiagarajan, and S.-M. Chen, "Nanocomposite of functionalized multiwall carbon nanotubes with nafion, nano platinum, and nano gold biosensing film for simultaneous determination of ascorbic acid, epinephrine, and uric acid". Analytical Biochemistry. 365(1): p. 122-131, (2007). DOI: https://doi.org/10.1016/j.ab.2007.02.034

[4]. Jakubec, P., et al., "Advanced sensing of antibiotics with magnetic gold nanocomposite: Electrochemical detection of chloramphenicol". 22(40): p. 14279-14284, (2016). DOI: https://doi.org/10.1002/chem.201602434

[5]. Sun, Y., et al., "Determination of chloramphenicol in food using nanomaterial-based electrochemical and optical sensors-A review". Food Chemistry. 410: p. 135434, (2023). DOI: https://doi.org/10.1016/j.foodchem.2023.135434

[6]. Xiao, S., et al., "Polyelectrolyte Multilayer-Assisted Immobilization of Zero-Valent Iron Nanoparticles onto Polymer Nanofibers for Potential Environmental Applications". ACS Applied Materials & Interfaces. 1(12): p. 2848-2855, (2009). DOI: https://doi.org/10.1021/am900590j

[7]. Rahmah, -.M.I., -.R.S. Sabry, and -.W.J. Aziz, - "Preparation and photocatalytic property of Fe2O3/ZnO composites with superhydrophobicity %J" - Int. J. Miner. Metall. Mater. - 28(- 6): p. - 1072, (2021). DOI: https://doi.org/10.1007/s12613-020-2096-y

[8]. La, D.D., et al. "Arginine-Mediated Self-Assembly of Porphyrin on Graphene: A Photocatalyst for Degradation of Dyes". Applied Sciences. 7, DOI: 10.3390/app7060643, (2017).

[9]. La, D.D., et al., (Arginine-Mediated Self-Assembly of Porphyrin on Graphene: A Photocatalyst for Degradation of Dyes". 7(6): p. 643, (2017). DOI: https://doi.org/10.3390/app7060643

[10]. Van Hoang, N., et al., "Green Synthesis of Fe/Graphene Nanocomposite Using Cleistocalyx operculatus Leaf Extract as a Reducing Agent: Removal of Pollutants (RhB Dye and Cr6+ Ions) in Aqueous Media". 7(47): p. e202203499, (2022). DOI: https://doi.org/10.1002/slct.202203499

[11]. Huyen, N.N., et al., "Boosting the Selective Electrochemical Signals for Simultaneous Determination of Chloramphenicol and Furazolidone in Food Samples by Using ZnFe2O4-Based Sensing Platform: Correlation between Analyte Molecular Structure and Electronic Property of Electrode Materials". Journal of The Electrochemical Society. 169(10): p. 106517, (2022). DOI: https://doi.org/10.1149/1945-7111/ac9715

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Published

25-08-2023

How to Cite

Nguyễn, T. X. Q., L. V. Lê, T. T. Nguyễn, M. H. Khổng, L. H. Nguyễn, Đức D. Lã, and P. D. Dang Trung. “Synthesis of Nanocomposites Material Fe/ GNPs/ Porphyrene and the Electrochemical Properties Investigation”. Journal of Military Science and Technology, vol. 89, no. 89, Aug. 2023, pp. 60-66, doi:10.54939/1859-1043.j.mst.89.2023.60-66.

Issue

Vol. 89 (2023)

Section

Research Articles

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