An evaluation of the combustion temperature profile of Ba(NO3)2-based composition
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https://doi.org/10.54939/1859-1043.j.mst.IPE.2024.110-117Keywords:
Barium nitrate; Combustion; Temperature profile; Condensed phase.Abstract
The study examined both theoretical and experimental combustion temperatures of
Ba(NO3)2-based samples of composition with an oxidizer excess coefficient of α~0.72 under various pressures. The results indicate that at low pressures, the combustion temperature of the samples is significantly lower than the calculated value. The temperature profile in the combustion wave at atmospheric pressure was determined, revealing that the samples exhibit a high surface combustion temperature. The majority of the heat required for the propagation of the sample's combustion is released in the condensed phase. These findings underscore the influence of pressure on combustion characteristics and emphasize the importance of considering phase interactions in understanding combustion behaviors.
References
[1]. Pulpea B. G., Nuță C.-V., Pulpea D., Rotariu A., Trană E., Toader G., Rotariu T., Dîrloman F., Șomoiag P., Ungureanu10 M. I., "Characterization of pyrotechnic composition used in tracer ammunitions". UPB Scientific Bulletin, Series B: Chemistry and Materials Science, 85, 2, (2023).
[2]. Kotter L. N., Groven L. J., "Nitrocellulose-Based Green-Light Illuminants: A Study of Barium Nitrate Particle Size on Spectral Performance". Propellants, Explosives, Pyrotechnics, 47, e202200214, (2022). DOI: https://doi.org/10.1002/prep.202200214
[3]. Ambekar A., Kim M., Lee W.-H., Yoh J. J., "Characterization of display pyrotechnic propellants: Burning rate". Applied Thermal Engineering, 121, 761-767, (2017). DOI: https://doi.org/10.1016/j.applthermaleng.2017.04.097
[4]. Ouyang D.-h., Guo S.-x., "Effect of nitrocellulose and polytetrafluoroethylene on the combustion characteristics of Ba (NO3) 2/Mg-containing pyrotechnic mixtures". SCIENCE AND TECHNOLOGY OF ENERGETIC MATERIALS, 75, 64-67, (2014).
[5]. Ouyang D.-h., "Effect of different binders on the combustion characteristics of Ba (NO3) 2/Mg-containing pyrotechnic mixtures". Central European Journal of Energetic Materials, 10, 209--215, (2013).
[6]. Denisyuk A. P., Duy Tuan N., Sizov V. A., "Combustion Behavior of the Inorganic Nitrates‐Based Compositions. Part II: Effect of Al and Al‐Mg Alloy on Burning Rate". Propellants, Explosives, Pyrotechnics, 47, e202100145, (2022). DOI: https://doi.org/10.1002/prep.202100145
[7]. Tuan N. D., A. P D., Khai D. M., V. A S., "Influence of some additives on burning rate of KNO3-based compositions". Vietnam Journal of Science and Technology, 61, 1000-1009, (2023). DOI: https://doi.org/10.15625/2525-2518/17077
[8]. Denisyuk A. P., Duy Tuan N., Sizov V. A., "Combustion Behavior of the Inorganic Nitrates‐Based Compositions Part I". Propellants, Explosives, Pyrotechnics, 45, 1382-1387, (2020). DOI: https://doi.org/10.1002/prep.202000053
[9]. Туан Н. З., Хунг Л., Денисюк А. П., "Определение экспериментальной температуры горения энергонасыщенных систем на основе нитратов калия, натрия и бария при атмосферном давлении". Успехи в химии и химической технологии, 32, 100-102, (2018).
[10]. Нгуен З. Т., Денисюк А., "Полнота горения композиций на основе нитратов различных металлов при атмосферном давлении". Вестник технологического университета, 22, 84-89, (2019).
[11]. Туан Н. З., Денисюк А. П., "Экспериментальная температура горения композиций на основе нитрата бария при различном давлении". Успехи в химии и химической технологии, 33, 90-92, (2019).
[12]. Денисюк А., Шепелев Ю., "Определение баллистических характеристик и параметров горения порохов и ТРТ". (2009)
[13]. Denisyuk A. P., Rusin D. L., Long N. D., "Mechanism of combustion of fire-extinguishing propellants based on potassium nitrate". Doklady Physical Chemistry, 414, 99-102, (2007). DOI: https://doi.org/10.1134/S0012501607050016
[14]. Синдицкий В., Егоршев В., Березин М., Серушкин В., "Методы исследования горения энергетических материалов". (2010)
[15]. Bardwell C. J., Bickley R. I., Poulston S., Twigg M. V., "Thermal decomposition of bulk and supported barium nitrate". Thermochimica Acta, 613, 94-99, (2015). DOI: https://doi.org/10.1016/j.tca.2015.05.013
[16]. Hosseini S. G., Eslami A., "Thermoanalytical investigation of relative reactivity of some nitrate oxidants in tin-fueled pyrotechnic systems". Journal of Thermal Analysis and Calorimetry, 101, 1111-1119, (2010). DOI: https://doi.org/10.1007/s10973-010-0813-x
[17]. Lengellé G., Duterque J., Trubert J. "Combustion of solid propellants"; DTIC Document, (2002).
[18]. Doyle E., Johnston P. K., Orzel R. A., "Phenolics: A literature review of thermal decomposition products and toxicity". J Am Coll Toxicol, 7, 201-220, (1988). DOI: https://doi.org/10.3109/10915818809014520
[19]. Jiang H., Wang J., Wu S., Yuan Z., Hu Z., Wu R., Liu Q., "The pyrolysis mechanism of phenol formaldehyde resin". Polymer Degradation and Stability, 97, 1527-1533, (2012). DOI: https://doi.org/10.1016/j.polymdegradstab.2012.04.016
