Synthesis of KOH-activated carbon aerogel for the efficient removal of crystal violet from aqueous solutions
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https://doi.org/10.54939/1859-1043.j.mst.VITTEP.2022.51-61Keywords:
Activated carbon aerogel; Efficent; Crystal violet.Abstract
In this study, a low-cost jackfruit based KOH-activated carbon aerogel (AJCA) is prepared from facile hydrothermal treatment synthesized core of jackfruit with different heating rate. AJCA is sythesisized to absorb crystal violet (CV) dye from aqueous solutions and effectively treat other dyes. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) allow for targeted analysis of sample surfaces which has many grooves of varying depth, and many layers of scales stack on top of each other. The specific surface area, which is examined by The Brunauer-Emmett-Teller (BET) method, reaches 592.65 m2/g. The most suitable heating rate is 3 degrees per minute (AJCA-3). The maximum adsorption capacity is 386,66 mg/g and the absorption performance reaches 96,5% at a concentration of 300 ppm, which indicates that AJCA-3 is very efficient and competitive with several adsorbents. The pseudo-second-order model satisfactorily describes the adsorption kinetics, and the Langmuir model was suitable to represent the adsorption equilibrium. These experiments show that AJCA has excellent potential on treating real coloured eflluents.
References
[1]. T.C.A. Siqueira, L.Z. da Silva, A.J. Rubio, R. Bergamasco, F. Gasparotto, EAd-S Paccola, et al. “Sugarcane bagasse as an efficient biosorbent for methylene blue removal: kinetics, isotherms and thermodynamics”, Int J Environ Res Publ Health, 17, p. 526, (2020). DOI: https://doi.org/10.3390/ijerph17020526
[2]. S. Noreen, M. Tahira, M. Ghamkhar, I. Hafiz, H.N. Bhatti, R. Nadeem, et al. “Treatment of textile wastewater containing acid dye using novel polymeric graphene oxide nanocomposites (GO/PAN,GO/PPy, GO/PSty)”, J Mater Res Technol, 14, pp. 25-35, (2021). DOI: https://doi.org/10.1016/j.jmrt.2021.06.007
[3]. Organization for Economic Co-operation and Development, Eco-Innovation in Industry, Enabling Green Growth, OECD Innovation Strategy, OECD, Paris, (2009).
[4]. P. Grassi, F.C. Drumm, S.S. Spannemberg, J. Georgin, D. Tonato, M.A. Mazutti, et al. “Solid wastes from the enzyme production as a potential biosorbent to treat colored effluents containing crystal violet dye”, Environ Sci Pollut Res, 27, pp. 10484-10494, (2020). DOI: https://doi.org/10.1007/s11356-020-07664-0
[5]. H. Ali, S.K. Muhammad, “Biosorption of crystal violet from the water on leaf biomass of Calotropis procera”, Environ Sci Technol 1, 143–150, (2008). DOI: https://doi.org/10.3923/jest.2008.143.150
[6]. R.F. Wang, L.G. Deng, K. Li, X.J. Fan, W. Li, H.Q. Lu, “Fabrication and characterization of sugarcane bagasse–calcium carbonate composite for the efficient removal of crystal violet dye from wastewater”, Ceram Int, 46, pp. 27484-27492, (2020). DOI: https://doi.org/10.1016/j.ceramint.2020.07.237
[7]. V. Buscio, V. López-Grimau, M.D. Álvarez, C. Gutiérrez-Bouzán, “Reducing the environmental impact of textile industry by reusing residual salts and water: ECUVal system”, ChemEng J 373, 161–170, (2019). DOI: https://doi.org/10.1016/j.cej.2019.04.146
[8]. C.R. Holkar, A.J. Jadhav, D.V. Pinjari, N.M. Mahamuni, A.B. Pandit, “A critical review on textile wastewater treatments: possible approaches”, J. Environ. Manag. 182, 351–366, (2016). DOI: https://doi.org/10.1016/j.jenvman.2016.07.090
[9]. Z. Jia, Z. Li, T. Ni, S. Li, “Adsorption of low-cost adsorption materials based on biomass (Cortaderia selloana flower spikes) for dye removal: kinetics, isotherms and thermodynamic studies”, J Mol Liq, 229, pp. 285-292, (2017). DOI: https://doi.org/10.1016/j.molliq.2016.12.059
[10]. K. Lee, L. Shabnam, S.N. Faisal, V.C. Hoang, V.G. Gomes, “Aerogel from fruit biowaste produces ultracapacitors with high energy density and stability”, Journal of Energy Storage 27, 101152, (2020). DOI: https://doi.org/10.1016/j.est.2019.101152
[11]. Maji, Subrata, et al. “High-Performance Supercapacitor Materials Based on Hierarchically Porous Carbons Derived from Artocarpus heterophyllus Seed”. ACS Applied Energy Materials, 4(11), 12257-12266, (2021). DOI: https://doi.org/10.1021/acsaem.1c02051
[12]. DAT, Nguyen Tien, et al. “Carbon sequestration through hydrothermal carbonization of expired fresh milk and its application in supercapacitor”. Biomass and Bioenergy, 143: 105836, (2020). DOI: https://doi.org/10.1016/j.biombioe.2020.105836
[13]. Dabrowski, A., “Adsorption - from theory to practice”. Advances in Colloid and Interface Science, 93: p. 135-224, (2001). DOI: https://doi.org/10.1016/S0001-8686(00)00082-8
[14]. Othman, N.H., et al., “Adsorption kinetics of methylene blue dyes onto magnetic graphene oxide”. Journal of Environmental Chemical Engineering, 6(2): p. 2803-2811, (2018). DOI: https://doi.org/10.1016/j.jece.2018.04.024
[15]. Gupta, N., A.K. Kushwaha, and M.C. Chattopadhyaya, “Application of potato (Solanum tuberosum) plant wastes for the removal of methylene blue and malachite green dye from aqueous solution”. Arabian Journal of Chemistry, 9: p. S707-S716, (2016). DOI: https://doi.org/10.1016/j.arabjc.2011.07.021
[16]. Akar, E., A. Altinişik, and Y. Seki, “Using of activated carbon produced from spent tea leaves for the removal of malachite green from aqueous solution”. Ecological Engineering, 52, p. 19-27, (2013). DOI: https://doi.org/10.1016/j.ecoleng.2012.12.032
[17]. Qiu, H., et al., “Critical review in adsorption kinetic models”. Journal of Zhejiang University-SCIENCE A, 10(5), p. 716-724, (2009).
[18]. K. Vasanth KumarV, R., Sivanesan, “Biosorption of malachite green, a cationic dye onto Pithophora sp., a fresh water algae”. Dyes and Pigments, 69, p. 102-107, (2006). DOI: https://doi.org/10.1016/j.dyepig.2005.02.005
[19]. Largitte, L. and R. Pasquier, “A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon”. Chemical Engineering Research and Design. 109, p. 495-504, (2016). DOI: https://doi.org/10.1016/j.cherd.2016.02.006
[20]. Qiu, H., et al., “Critical review in adsorption kinetic models”. Journal of Zhejiang University-science a. 10(5), p. 716-724, (2009). DOI: https://doi.org/10.1631/jzus.A0820524
[21]. Y. S. Ho, G.M., “The kinetics of sorption of divalent metal ions onto sphagnum moss peat”. Water Research. 34(3), p. 735-742, (2000). DOI: https://doi.org/10.1016/S0043-1354(99)00232-8
[22]. C. Hessel, C. Allegre, M. Maisseu, F. Charbit, P. Moulin, “Guidelines and legislation for dye house effluents”, J. Environ. Manag. 83 (2), 171–180, (2007). DOI: https://doi.org/10.1016/j.jenvman.2006.02.012
[23]. Qingsong Ji, Haichao Li, “High surface area activated carbon derived from chitin for efficient adsorption of Crystal Violet”, Diamond and Related Materials, 118, 108516, (2021). DOI: https://doi.org/10.1016/j.diamond.2021.108516
[24]. Annadurai, G., Juang, R.-S., & Lee, D.-J. “Use of cellulose-based wastes for adsorption of dyes from aqueous solutions”. Journal of Hazardous Materials, 92, 263–274, (2004). DOI: https://doi.org/10.1016/S0304-3894(02)00017-1
[25]. Atmani, F., Bensmaili, A., & Mezenner, N. Y. “Synthetic textile effluent removal by skin almond waste”. Journal of Environmental Science and Technology, 2, 153–169, (2009). DOI: https://doi.org/10.3923/jest.2009.153.169
[26]. Chowdhury, S., Mishra, R., Saha, P., & Kushwaha, P. “Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk”. Desalination, 265, 159–168, (2011). DOI: https://doi.org/10.1016/j.desal.2010.07.047
[27]. Druzian, Susanne P., et al. “Chitin-psyllium based aerogel for the efficient removal of crystal violet from aqueous solutions”. International Journal of Biological Macromolecules, 179, 366-376, (2021). DOI: https://doi.org/10.1016/j.ijbiomac.2021.02.179
[28]. Gong, Xiao-Li, et al. "Effective adsorption of crystal violet dye on sugarcane bagasse–bentonite/sodium alginate composite aerogel: Characterisation, experiments, and advanced modelling." Separation and Purification Technology, 286, 120478, (2022). DOI: https://doi.org/10.1016/j.seppur.2022.120478
[29]. Gopakumar, Deepu A., et al. "Robust superhydrophobic cellulose nanofiber aerogel for multifunctional environmental applications." Polymers 11.3, 495, (2019). DOI: https://doi.org/10.3390/polym11030495
[30]. Liu, Cuiyun, et al. "In situ reduced and assembled three-dimensional graphene aerogel for efficient dye removal." Journal of Alloys and Compounds 714: 522-529, (2017). DOI: https://doi.org/10.1016/j.jallcom.2017.04.245
