Synthesis, optical properties and energy transfer in ZnO nanocrystals co-doped with Ce3+ and Tb3+ ions
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https://doi.org/10.54939/1859-1043.j.mst.84.2022.101-108Keywords:
ZnO; Ce3 and Tb3 ions; Doped; Optical properties; Energy transfer.Abstract
ZnO nanocrystals (NCs) co-doped with Ce3+ and Tb3+ ions were successfully synthesized by Sol-Gel method. The presence and content of elements in the sample were determined through energy dispersive spectroscopy (EDX). The structure, crystal size of ZnO NCs co-doped with rare earth ions (RE) were investigated by using X-ray diffraction (XRD). The optical properties of ZnO NCs co-doped with Ce3+ and Tb3+ ions were investigated through excitation and fluorescence spectroscopy. The energy transfer process from Ce3+ ions to Tb3+ ions has been studied and explained in detail. The ZnO NCs co-doped with Ce3+ and Tb3+ ions are completely non-toxic and can can be controlled the optical properties by varying the Tb concentration. The results of this study show many possible applications of the material in the fields of lighting and biomarkers.
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