Thermoluminescent properties of CaF2 co-doped Er3+, Li+ ions

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Authors

  • Vu Thi Thai Ha (Corresponding Author) Institute of Materials Science, Vietnam Academy of Science and Technology
  • Do Thi Anh Thu Institute of Materials Science, Vietnam Academy of Science and Technology
  • Doan Tuan Anh Institute of Materials Science, Vietnam Academy of Science and Technology
  • Nguyen Trong Thanh Institute of Materials Science, Vietnam Academy of Science and Technology

DOI:

https://doi.org/10.54939/1859-1043.j.mst.85.2023.88-94

Keywords:

Nanomaterial; Thermoluminescence (TL); CaF2, Li ions.

Abstract

CaF2 nanomaterial co-doped Er3+ and Li+ were synthesized by precipitation method. The structure, morphology and composition of the materials were investigated through X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). The thermoluminescent properties of materials have been studied; The results show that the concentration of Li+ ions has an effect on the thermoluminescence intensity of the material. The kinetic parameters of the traps corresponding to the main peak were determined using TLAnal program for analysis of experimental data.

References

[1]. J.W. PostonSr., “Encyclopedia of Physical Science and Technology” (Third Edition), pp. 603 - 650, (2003). DOI: https://doi.org/10.1016/B0-12-227410-5/00185-X

[2]. C. M. Sunta, “A Review of Thermoluminescence of Calcium Fluoride, Calcium Sulphate and Calcium Carbonate”, Radiat. Protect. Dosim. Vol. 8(1), pp. 25 – 44, (1984). DOI: https://doi.org/10.1093/oxfordjournals.rpd.a083041

[3]. Mikhail Danilkin, Aime Lust, Mihkel Kerikmäe, Viktor Seeman, Hugo Mändar, Mare Must, “CaF2:Mn extreme dosimeter: Effects of Mn concentration on thermoluminescence mechanisms and properties”, Radiation Measurements Vol. 41, Iss. 6, pp. 677-681, (2006). DOI: https://doi.org/10.1016/j.radmeas.2006.04.020

[4]. Mckeever, S.W. S. “Themoluminescence of Solids”. Cambridge University Press, Cambridge, England, pp. 231 – 232, (1988).

[5]. Viviane K. Asfora, Patrícia L. Antonio, Josemary A.C. Gonçalves, Carmen C. Bueno, Vinicius S.M. de Barros, Charles N.P. Oliveira, Linda V.E. Caldas, Helen J. Khoury, “Evaluation of TL and OSL responses of CaF2:Tm for electron beam processing dosimetry”, Radiation Measurements, Vol. 140, 106512, (2021). DOI: https://doi.org/10.1016/j.radmeas.2020.106512

[6]. M. Manhas, Vinay Kumar, Visha Sharma, O.M. Ntwaeaborwa, H.C. Swart, “Effect of alkali metal ions (Li+, Na+ and K+) on the luminescence properties of CaMgB2O5: Sm3+ nanophosphor”, Nano-Structures & Nano-Objects, Vol. 3, pp. 9–16, (2015). DOI: https://doi.org/10.1016/j.nanoso.2015.06.003

[7]. Vũ Thị Thái Hà, Đỗ Thị Anh Thư, Ứng Thị Diệu Thúy, Nguyễn Thanh Hường, Nguyễn Tú Oanh, Chế tạo và nghiên cứu tính chất quang của vật liệu CaF2 pha tạp ion Er3+”, Tạp chí Hóa học, số 57(4e1,2), pp. 219-222, (2019).

[8]. Nguyen Thi Quy Hai,· Tran Kim Anh, Pham Thi Minh Chau, ·Vu Thi Thai Ha,·Ho Van Tuyen,·Tran Thu Huong, Ha Thi Phuong,· Quoc Le Minh, “Multistep synthesis and upconversion luminescence of spherical Gd2O3:Er and Gd2O3:Er @silica”, Journal of Materials Science: Materials in Electronics Vol. 31, pp.3354–3360, (2020). DOI: https://doi.org/10.1007/s10854-020-02883-0

[9]. I.Kaminska, D. Elbaum, B. Sikora, P. Kowalik, J. Mikulski, Z. Felcyn, P. Samol, T. Wojciechowski, R. Minikayev, W. Paszkowicz, W. Zaleszczyk, M. Szewczyk, A. Konopka, G. Gruzeł, M. Pawlyta, M. Donten, K. Ciszak, K. Zajdel, M. Frontczak-Baniewicz, P. Stępień, M. Łapiński, G. Wilczyński, K. Fronc, “Single-step synthesis of Er3+ and Yb3+ ions doped molybdate/Gd2O3 core-shell nanoparticles for biomedical imaging”, Nanotechnology Vol. 29 (2), 025702, pp. 1 – 19, (2018). DOI: https://doi.org/10.1088/1361-6528/aa9974

[10]. H Hristov, Y Baneva, D Nedeva, N Arhangelova, I Penev, V Velev, G Moschini, P Rossi and N M Uzunov, “Thermoluminescence properties of Eu and Li co-doped Gd2O3, induced by UV light”, Journal of Physics: Conference Series 398, 012043, (2012). DOI: https://doi.org/10.1088/1742-6596/398/1/012043

[11]. Xu Huibing, Zhuang Weidong, Wen Xiaofan, Liu Ronghui, Hu Yunsheng, Xia Tian, “Effect of Li+ ions doping on structure and luminescence of (Y,Gd)BO3:Tb3+”. J.Rare Earths, Vol. 28, pp. 701 – 704, (2010). DOI: https://doi.org/10.1016/S1002-0721(09)60183-6

[12]. Partha P. Pal, J. Manam, “Effect of Li+ co-doping on the luminescence properties of ZnO:Tb3+ nanophosphors”, Nanosystems: Physics, Chemistry, Mathematics Vol. 4 (3), pp. 395–404, (2013).

[13]. GW Jung, K Park, “Effect of monovalent charge compensators on the photoluminescence properties of Ca3(PO4)2:Tb3+, A+ (A= Li, Na, K) phosphors”, Journal of Materials Science & Technology, Vol. 82, pp 187-196, (2021). DOI: https://doi.org/10.1016/j.jmst.2020.11.065

[14]. Xinmiao Yu, Zhendong Liu, Wentao Zhang, Xinru Xu, Haiying Du, “Effect of A+ (A = Li, Na and K) co-doping on enhancing the luminescence of Ca5(PO4)2SiO4:Eu3+ red-emitting phosphors as charge compensator”, Ceramics International, Vol. 47, Iss. 3, pp 3540-3547, (2021). DOI: https://doi.org/10.1016/j.ceramint.2020.09.198

[15]. Yingying Ma, Shigao Chen, Junzhi Che, Jianxu Wang, Ruyi Kang, Jin Zhao, Bin Deng, Ruijin Yu, Huiling Geng, “Effect of charge compensators (Li+, Na+, K+) on the luminescence properties of Sr3TeO6:Eu3+ red phosphor”, Ceramics International, Vol. 47, Iss. 6, pp 8518-8527, (2021). DOI: https://doi.org/10.1016/j.ceramint.2020.11.219

Published

28-02-2023

How to Cite

Vũ, H., T. Đỗ, A. Đoàn, and T. Nguyễn. “Thermoluminescent Properties of CaF2 Co-Doped Er3+, Li+ Ions”. Journal of Military Science and Technology, vol. 85, Feb. 2023, pp. 88-94, doi:10.54939/1859-1043.j.mst.85.2023.88-94.

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Section

Research Articles

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