Effect of nanosilica and nano zirconium oxide mixture modified by polydimethyl siloxane on the heat resistance of silicone paint
7 viewsDOI:
https://doi.org/10.54939/1859-1043.j.mst.104.2025.112-121Keywords:
Silicone paint; Nanosilica; Nano zirconium oxide; Polydimethyl siloxane; High-temperature resistant paint.Abstract
Silicone-based paints are known for their high-temperature resistance and durability in chemical environments. This paper presents research findings on a silicone paint formulation supplemented with a mixture of nano-silica and nano-zirconium oxide, which has been surface-modified with Polydimethylsiloxane (PDMS). The incorporated ratio was 0.45% modified nano-silica and 1.05% modified nano-zirconium oxide. Following thermal endurance evaluation (a thermal shock test conducted at 1,050 °C for 25 seconds), no micro-cracks were observed on the surface. This is attributed to the increased flexibility of the silicone coating at high temperatures and the more uniform dispersion of the modified nano-additive particles within the silicone resin matrix, thereby enhancing the thermal resistance of the paint film. The author also conducted a comparative heat resistance test using an acetylene torch, with the sample plate's exposure temperature reaching approximately 1,100 °C for a duration of 25 to 30 seconds. The performance of the modified nano-particle-containing silicone paint was compared against the BKV inorganic heat-resistant paint and alkyd paint on steel test panels from a CT-18 engine, yielding favorable results.
References
[1]. Nguyen Van Loc, “Paint Technology”, Education Publishing House, pp. 7-10, (2008).
[2]. Hanqi Qian, Bo Jiang, “Silicone resin applications for heat-resistant coatings: a review”, Polymer Science, Series C, Vol. 65(2), pp. 206-219, (2023). DOI: https://doi.org/10.1134/S1811238223700443
[3]. Nguyen Trung Thanh, “Study on effects of isocyanate on some properties of epoxy varnish”, Vi-etnam Journal of Chemistry, Vol. 60(1), pp. 15-20, (2022) . DOI: https://doi.org/10.1002/vjch.202100030
[4]. Hao Li, Yujie Qiang, Wenjie Zhao, Shengtao Zhang, “2-Mercaptobenzimidazole-inbuilt metal-organic-frameworks modified graphene oxide towards intelligent and excellent anti-corrosion coat-ing”, Corrosion Science, Vol. 191, pp.109715, (2021). DOI: https://doi.org/10.1016/j.corsci.2021.109715
[5]. Xin Yuan , Rongcao Yu , Yilin Du , Bing Lei, “EIS study on the barrier properties of silicone-epoxy coatings enhanced by different PDA-BN@ZnO nano-pigment contents”, Corrosion Science, Vol. 228, pp. 111810, (2024). DOI: https://doi.org/10.1016/j.corsci.2023.111810
[6]. A. M. Kamalan Kirubaharan, M. Selvaraj, K. Maruthan, D. Jeyakumar, “Synthesis and characteriza-tion of nanosized titanium dioxide and silicon dioxide for corrosion resistance applications”, Jour-nal of Coatings Technology and Research, Vol. 9(2), pp. 163-170, (2012). DOI: https://doi.org/10.1007/s11998-009-9226-9
[7]. Nguyen Ba Ngoc, Nguyen Trung Thanh, Trinh Duc Cong, Nguyen Van Khoi, Tran Vu Thang, "Influ-ence of nanosilica on the properties of silicone paint", Vietnam Journal of Chemistry, Vol. 55(E34), pp. 152-155, (2017).
[8]. Jiaqing Zhang, Yi Guo, Lingxin He, Jie Huang, YuBiao Huang, Fengju Shang, Rui Liu, Xia Zhou, “Study on preparation and fire-resistant property of an organic silicone coating with compounding glass powder”, Journal of Coatings Technology and Research, Vol. 22, pp. 1087-1097, (2025). DOI: https://doi.org/10.1007/s11998-024-01035-x
[9]. Andreza P. Cardoso, Stéphanie C. de Sá, Carlos H. M. Beraldo, Gelsa E. N. Hidalgo, Carlos A. Fer-reira, “Intumescent coatings using epoxy, alkyd, acrylic, silicone, and silicone-epoxy hybrid resins for steel fire protection”, Journal of Coatings Technology and Research, Vol. 17(6), pp.1471-1488, (2020). DOI: https://doi.org/10.1007/s11998-020-00366-9
[10]. Nguyen Trung Thanh, “Improvement of physical and thermal properties of polyvinyl butyral coating with nanosilica”, Suan Sunandha Science and Technology Journal, Vol. 10(1), pp.1-8, (2023). DOI: https://doi.org/10.53848/ssstj.v10i1.408
[11]. A.Mathiazhagan, Rani Joseph, “Nanotechnology - A new prospective in organic coating – Review”, International Journal of Chemical Engineering and Applications, Vol. 2(4), pp. 225-237, (2011). DOI: https://doi.org/10.7763/IJCEA.2011.V2.108
[12]. Sara Lopez de Armentia, Mariola Pantoja, Juana Abenojar, Miguel Angel Martinez, “Development of silane-based coatings with zirconia nanoparticles combining wetting, tribological, and aesthetical properties”, Coatings, Vol. 8(10), (2018). DOI: https://doi.org/10.3390/coatings8100368
[13]. Nguyen Van Chi, Pham Trung San, Le Thi Nhung, Truong Anh Khoa, Nguyen Hoang, Nguyen Thu Hien, “The influence of ZrO2/Silane pretreatment on corosion resistance of powder coating”, Vi-etnam Journal of Science and Technology, Vol. 56(3B), pp. 35-41, (2018).
[14]. Nguyen Ba Ngoc, Nguyen Trung Thanh, Nguyen Van Gioi, Truong Dinh Tuan, Trinh Duc Cong, Nguyen Van Khoi, "Influence of Nano Zirconium Oxide on the Properties of Silicone Paint", Journal of Military Science and Technology, Vol. 64, pp. 152-159, (2019).
[15]. Lun Qi, Xiaolong Weng, Le Yuan, Biao Wei, Xueyu Wu, Gang Huang, Xingbo Du, Hongxing Liu, “Improved thermal expansion performance of aluminum/polysiloxane/glass coatings with low infra-red emissivity by zinc powder”, Infrared Physics and Technology, Vol. 110, pp. 103458, (2020). DOI: https://doi.org/10.1016/j.infrared.2020.103458
[16]. Lun Qi, Xiaolong Weng, Biao Wei, Le Yuan, Gang Huang, Xingbo Du, Xueyu Wu, Hongxing Liu, “Effects of low-melting glass powder on the thermal stabilities of low infrared emissivity Al/polysiloxane coatings”, Progress in Organic Coatings, Vol. 142, pp. 105579, (2020). DOI: https://doi.org/10.1016/j.porgcoat.2020.105579
[17]. Gan Qimao, Lian Yanyuan, Yang Weiguang, Xiao Tingting, Wang Li, Zhang Yan, Zhang Xiaohong, Huang Ronghua, “Methyl methacrylate modified silicone coats for metallic corrosion protec-tion”, Wuhan University Journal of Natural Sciences, Vol. 64(1), pp. 46-52, (2018).
[18]. Nguyen Trung Thanh, “Influence of nanosilica on the properties of nanocomposite based on K-153 epoxy resin”, Suan Sunandha Science and Technology Journal, Vol. 9(1), pp. 5-11, (2022).
[19]. Sensen Han, Qingshi Meng, Ke Xing, Sherif Araby, Yin Yu, Adrian Mouritz, Jun Ma, “Epoxy/graphene film for lifecycle self-sensing and multifunctional applications”, Composites Sci-ence and Technology, Vol. 198, pp. 108312, (2020). DOI: https://doi.org/10.1016/j.compscitech.2020.108312
[20]. Haopeng Wang, Jihu Wang, Shaoguo Wen, Sihong Jiang, Jia Song, Shengnan Ding, Hui Wu, “Prepa-ration of Silicone Coating and Its Anti-Ice and Anti-Corrosion Properties”, Coatings, Vol. 14, pp. 699, (2024). DOI: https://doi.org/10.3390/coatings14060699